Here are steps to follow:
1) Right click on your desktop and go to New > Shortcut.
2) In create shortcut window, type gtalk:chat?jid=username@gmail.com. Where username is gmail id of your friend.
3) Click ok.
Its done.
You can also make shortcut to call your friend for that you have to write gtalk:call?jid=username@gmail.com.
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